Nuclear Physics and Atomic Energy

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Nuclear Physics and Atomic Energy

  ISSN: 1818-331X (Print), 2074-0565 (Online)
  Publisher: Institute for Nuclear Research of the National Academy of Sciences of Ukraine
  Languages: Ukrainian, English, Russian
  Periodicity: 4 times per year

  Open access peer reviewed journal


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Nucl. Phys. At. Energy 2018, volume 19, issue 3, pages 252-257.
Section: Radiation Physics.
Received: 02.05.2018; Accepted: 11.10.2018; Published online: 04.12.2018.
PDF Full text (ua)
https://doi.org/10.15407/jnpae2018.03.252

Small-angle neutron scattering by liquid systems of fullerenes Ñ60 and Ñ70

L. A. Bulavin1,2, T. V. Nagorna1,2,*, D. Chudoba3,4, O. A. Kyzyma1,3, O. I. Ivankov2,3

1 Taras Shevchenko National University of Kyiv, Kyiv, Ukraine
2 Institute for Safety Problems of Nuclear Power Plants, National Academy of Sciences of Ukraine, Kyiv, Ukraine
3 Joint Institute for Nuclear Research, Dubna, Russia
4Adam Mickiewicz University in Poznan, Poznan, Poland


*Corresponding author. E-mail address: nagorna@jinr.ru

Abstract: Results of studies of the cluster state of fullerenes C60 and C70 in a solution of toluene with acetonitrile, performed by small-angle neutron scattering are presented. The experiment has been carried out using the small-angle scattering spectrometer YuMO, located at the IBR-2 reactor of the Joint Institute for Nuclear Research (Dubna). It has shown that a content of acetonitrile in the solution is increased, the agglomerated fraction was increasing. Sharp tendency to aggregation was observed after the certain threshold value of acetonitrile concentration was exceeded. The processes of C60 and C70 fullerenes’ cluster formation were analyzed in comparison.

Keywords: liquid systems of fullerenes, fullerene clusterization, small-angle neutron scattering.

References:

1. L. Wang. Solvated fullerenes, a new class of carbon materials suitable for high-pressure studies: A review. J. Phys. Chem. Solids 84 (2015) 85. https://doi.org/10.1016/j.jpcs.2014.06.007

2. M. Xing, R. Wang, J. Yu. Application of fullerene C60 nano-oil for performance enhancement of domestic refrigerator compressors. Int. J. Refrigeration 40 (2014) 398. https://doi.org/10.1016/j.ijrefrig.2013.12.004

3. S. Afreen et al. Functionalized fullerene (C60) as a potential nanomediator in the fabrication of highly sensitive biosensors. Biosensors and Bioelectronics 63 (2015) 354. https://doi.org/10.1016/j.bios.2014.07.075

4. A.V. Eletskij, B.M. Smirnov. Fullerenes and carbon structures. Phys. Uspekhi 38(9) (1995) 935. https://doi.org/10.1070/PU1995v038n09ABEH000103

5. Y. Marcus. Solubilities of buckminsterfullerene and sulfur hexafluoride in various solvents. J. Phys. Chem. B 101(42) (1997) 8617. https://doi.org/10.1021/jp970671s

6. Y. Marcus et al. Solubility of C60 fullerene. J. Phys. Chem. B 105(13) (2001) 2499. https://doi.org/10.1021/jp0023720

7. A.N. Kinchin, A.M. Kolker, N.I. Islamova. Correlation of the thermodynamic parameters of the fullerene C60 solution with the properties of non-aqueous solvents. Zhurnal Fizicheskoj Khimii 76(10) (2002) 1772. (Rus)

8. J. Labille et al. Affinity of C60 fullerenes with water. Fullerenes, Nanotubes Carb. Nanostr. 14 (2006) 307. https://doi.org/10.1080/15363830600665250

9. I.E. Serdyuk et al. Preparation and biological activity of aqueous colloidal solutions of fullerenes C60 and C70 mixtures. Biotekhnologiya 4(5) (2011) 64. (Rus)

10. M. Alfe, B. Apicella, R. Barbella. Aggregation and interactions of C60 and C70 fullerenes in neat N-methylpyrrolidinone and N-methylpyrrolidinone/toluene mixtures. Chem. Phys. Lett. 405 (2005) 193. https://doi.org/10.1016/j.cplett.2005.02.030

11. A. Mrzel et al. Investigation of encapsulation and solvatochromism of fullerenes in binary solvent mixtures. J. Phys. Chem. B 103(51) (1999) 11256. https://doi.org/10.1021/jp992637e

12. N.P. Yevlampieva et.al. Aggregation of fullerene C60 in N-methylpyrrolidone. Colloids and Surfaces A: Physicochemical and Engineering Aspects 209 (2002) 167. https://doi.org/10.1016/S0927-7757(02)00177-2

13. V.L. Aksenov et al. Study of fullerene aggregates in pyridine/water solutions. AIP Conf. Proc. 591 (2001) 66. https://doi.org/10.1063/1.1426823

14. V.L. Aksenov et al. Effect of the age of the C60/N-methyl-2-pyrrolidone solution on the structure of clusters in the C60/N-methyl-2-pyrrolidone/water system according to the small-angle neutron scattering data. Crystallogr. Rep. 52(3) (2007) 479. https://doi.org/10.1134/S106377450703025X

15. V.L. Aksenov et al. Formation of fullerene clusters in the system C60/NMP/water by SANS. Physica B: Condensed Matter 385-386 (2006) 795. https://doi.org/10.1016/j.physb.2006.06.086

16. E.A. Kizima et al. Reorganization of fullerene clusters in the C60/N-methyl-2-pyrrolidone/water system. Poverkhnost 12 (2008) 1. (Rus)

17. H.N. Glosh, A.V. Sapre, J.P. Mittal. Aggregation of C70 in Solvent Mixtures. J. Phys. Chem. 100(22) (1996) 9439. https://doi.org/10.1021/jp9535046

18. A.V. Eletskii, M.V. Okun', V.N. Bezmel'nitsyn. Fullerenes in solutions. Phys. Uspekhi 41 (1998) 1091. https://doi.org/10.1070/PU1998v041n11ABEH000502

19. Y. Wang. Photophysical Properties of Fullerenes and Fullerene/N,N-Diethylanilhe Charge-Transfer Complexes. J. Phys. Chem. 96(2) (1992) 764. https://doi.org/10.1021/j100181a044

20. Y.-P. Sun, C. E. Bunker, B. Ma. Quantitative Studies of Ground and Excited State Charge Transfer Complexes of Fullerenes with N,N-Dimethylaniline and N,N-Diethylaniline. J. Am. Chem. Soc. 116(21) (1994) 9692. https://doi.org/10.1021/ja00100a039

21. L.A. Bulavin et al. Fullerene Clustering in C70/N-methyl-2-pyrrolidone/toluene Liquid System. Ukr. J. Phys. 63(2) (2018) 116. https://doi.org/10.15407/ujpe63.2.116

22. V.L. Aksenov et al. Formation of C60 Fullerene Clusters in Nitrogen Containing Solvents. Physics of the Solid State 52(5) (2010) 1059. https://doi.org/10.1134/S1063783410050367

23. T.V. Nagorna et al. Temporal solvatochromic effect in ternary C70/toluene/N-methyl-pyrrolidine-2-one solution. J. Mol. Liq. 235 (2017) 111. https://doi.org/10.1016/j.molliq.2016.12.017

24. Y.M. Ostanevich. Time-of-flight small-angle scattering spectrometers on pulsed neutron sources. Macromol. Chem., Macromol. Symp. 15 (1988) 91. https://doi.org/10.1002/masy.19880150107

25. A.I. Kuklin et al. Optimization of the two-detector system of a small-angle neutron spectrometer YuMO for the study of nanoobjects. Poverkhnost 6 (2006) 73. (Rus)

26. A. Kuklin et al. Analysis of neutron spectra and fluxes obtained with cold and thermal moderators at IBR-2 reactor: Experimental and computer-modeling studies. Physics of Particles and Nuclei Letters 8 (2011) 119. https://doi.org/10.1134/S1547477111020075

27. V.N. Shvetsov. Neutron Sources at the Frank Laboratory of Neutron Physics of the Joint Institute for Nuclear Research. Quantum Beam Sci. 1(1) (2017) 6. https://doi.org/10.3390/qubs1010006

28. Yu.I. Prylutskyy et al. On the origin of C60 fullerene solubility in aqueous solution. Langmuir 30(14) (2014) 3967. https://doi.org/10.1021/la404976k

29. R.S. Ruoff et al. Solubility of C60 in a variety of solvents. J. Phys. Chem. 97(13) (1993) 3379. https://doi.org/10.1021/j100115a049

30. X. Zhou et al. Solubility of Fullerene C60 and C70 in Toluene, o-Xylene and Carbon Disulfide at Various Temperatures. Fullerene Sci. Technol. 5(1) (1997) 285. https://doi.org/10.1080/15363839708011990

31. W.A. Scrivens, J.M. Tour. Potent solvents for C60 and their utility for the rapid acquisition of 13C NMR data for fullerenes. J. Chem. Soc. Chem. Commun. 15 (1993) 1207. http://dx.doi.org/10.1039/C39930001207

32. N. Sivaraman et al. Solubility of C70 in organic solvents. Fullerene Sci. Technol. 2(3) (1994) 233. https://doi.org/10.1080/15363839408009549

33. A.V. Nikolaev et al. Molecular structure of the C70 fullerene. Chem. Phys. Lett. 223 (1994) 143. https://doi.org/10.1016/0009-2614(94)00432-3

34. A.A. Kaznacheevskaya et al. Reorganization of the cluster state in a C60/N-Methylpyrrolidone/water solution: Comparative characteristics of dynamic light scattering and small-angle neutron scattering data. J. Surf. Invest. 7(6) (2013) 1133. https://doi.org/10.1134/S102745101306030X

35. M.V. Avdeev et al. Structural features of molecular-colloidal solutions of C60 fullerenes in water by small-angle neutron scattering. Langmuir 20(11) (2004) 4363. https://doi.org/10.1021/la0361969