Nuclear Physics and Atomic Energy

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Nuclear Physics and Atomic Energy

  ISSN: 1818-331X (Print), 2074-0565 (Online)
  Publisher: Institute for Nuclear Research of the National Academy of Sciences of Ukraine
  Languages: Ukrainian, English
  Periodicity: 4 times per year

  Open access peer reviewed journal


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Nucl. Phys. At. Energy 2022, volume 23, issue 3, pages 212-215.
Section: Engineering and Methods of Experiment.
Received: 26.07.2022; Accepted: 09.11.2022; Published online: 27.11.2022.
PDF Full text (ua)
https://doi.org/10.15407/jnpae2022.03.212

Alkyl derivative of p-terphenyl as an activator of polysiloxane-based scintillator

P. Ì. Zhmurin, D. A. Yelisieiev, V. D. Alekseev, O. V. Yelisieieva*, Yu. Î. Íurkalenko

Institute of Scintillation Materials, STC “Institute for Single Crystals”, National Academy of Sciences of Ukraine, Kharkiv, Ukraine

*Corresponding author. E-mail address: osvidlo@i.ua

Abstract: One of the problems in creating a radiation-hard scintillation composition on a polysiloxane base is the search for a radiation-hard activator capable of dissolving in such a base in sufficient quantity. In this work, in order to improve the solubility of p-terphenyl molecules in a polysiloxane base, its structure was modified with tert-butyl substituents. The obtained alkyl derivative of p-terphenyl was used as an activator of polysiloxane-based scintillators. The optical and scintillation properties of the obtained polysiloxane-based scintillators were studied, and their radiation hardness was determined.

Keywords: p-terphenyl, activator, polysiloxane scintillator, light yield, radiation hardness.

References:

1. A. Artikov et al. Design and construction of new central and forward muon counters for CDF II. Nucl. Instrum. Meth. A 538(1-3) (2005) 358. https://doi.org/10.1016/j.nima.2004.09.009

2. D.G. Michael et al. The magnetized steel and scintillator calorimeters of the MINOS experiment. Nucl. Instrum. Meth. A 596(2) (2008) 190. https://doi.org/10.1016/j.nima.2008.08.003

3. J.K. Walker, A.R. Katritzky, Z. Degaszfaran. Radiation resistance of polysiloxane based scintillators doped with oxadiazole fluors. Chemica Scripta 29(3) (1989) 245.

4. J. Harmon et al. Linear polydiorganosiloxanes as plastic bases for radiation hard scintillators. Nucl. Instrum. Meth. B 53(3) (1991) 309. https://doi.org/10.1016/0168-583X(91)95619-O

5. J.B. Birks. The Theory and Practice of Scintillation Counting (London: Pergamon Press, 1964) 684 ð. Book

6. B.V. Grynyov, V.G. Senchyshyn. Plastic Scintillators (Kharkiv: Akta, 2003) 324 p. (Ukr)

7. V.G. Senchishin et al. Radiation resistance investigation of SCSN-81T, BC-408, UPS923A and UPS98RH plastic scintillators. Functional Materials 10(2) (2003) 281. http://functmaterials.org.ua/contents/10-2/FM102-30.pdf

8. Patent UA103443, IPC G01T 1/203 (2006.01), published on 10.10.2013, Bull. No. 19. (Ukr)

9. E. Kowalski, R. Anliker, K. Schmid. Performance parameters of some new efficient and highly soluble solutes for liquid scintillators. Molecular Crystals 4(1-4) (1968) 403. https://doi.org/10.1080/15421406808082926

10. I. Berlman. Handbook of Fluorescence Spectra of Aromatic Molecules. 2nd ed. (Academic Press, 1971) 488 p. Book

11. A. Quaranta et al. Characterization of polysiloxane organic scintillators produced with different phenyl containing blends. Materials Chemistry and Physics 137(3) (2013) 951. https://doi.org/10.1016/j.matchemphys.2012.10.041

12. P.Ì. Zhmurin et al. Radiation hardness of polysiloxane-based scintillators. Problems of Atomic Science and Technology 2 (2022) 38. https://doi.org/10.46813/2022-137-095